Twisted Bonds (The Camorra Chronicles Book 4)

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Steady-state absorption spectra were measured by Perkin Elmer (Lambda 950) spectrophotometer. The detailed setups of the light source and transient absorption spectroscopy are described in Supplementary Information. Magnetic properties

Synthesis, structural analysis, and properties of highly

Ni, Y. et al. A Chichibabin’s hydrocarbon-based molecular cage: The impact of structural rigidity on dynamics, stability, and electronic properties. J. Am. Chem. Soc. 142, 12730–12742 (2020). Kang, HW., Liu, YC., Shao, WK. et al. Synthesis, structural analysis, and properties of highly twisted alkenes 13,13’-bis(dibenzo[ a, i]fluorenylidene) and its derivatives. Régimbald-Krnel, M. & Wentrup, C. On the di-1-naphthylcarbene−dibenzofluorene rearrangement and the ethylenization of diarylcarbinols. J. Org. Chem. 63, 8417–8423 (1998). Nishiuchi, T., Aibara, S., Sato, H. & Kubo, T. Synthesis of π‐extended Thiele’s and Chichibabin’s hydrocarbons and effect of the π‐congestion on conformations and electronic states. J. Am. Chem. Soc. 144, 7479–7488 (2022).

Shvo, Y. & Shanan-Atidi, H. Internal rotation in olefins. I. Kinetic investigation by nuclear magnetic resonance. J. Am. Chem. Soc. 91, 6683–6689 (1969).

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Tschitschibabin, A. E. Über einige phenylierte derivate des p,p-Ditolyls. Ber. Dtsch. Chem. Ges. 40, 1810–1819 (1907). Kanawati, B., Genest, A., Schmitt-Kopplin, P. & Lenoir, D. Bis-dibenzo[a.i]fluorenylidene, does it exist as stable 1,2-diradical? J. Mol. Model. 18, 5089–5095 (2012).Barclay, T. M. et al. The heterocyclic diradical benzo-1,2:4,5-bis(1,3,2-dithiazolyl). electronic, molecular and solid state structure. J. Am. Chem. Soc. 119, 2633–2641 (1997). Wentrup, C., Regimbald‐Krnel, M. J., Müller, D. & Comba, P. A thermally populated, perpendicularly twisted alkene triplet diradical. Angew. Chem. Int. Ed. 55, 14600–14605 (2016).

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Saltiel, J. & Charlton, J. L. Cis-trans isomerization of olefins in Rearrangements in Ground and Excited States (ed. de Mayo, P.), Vol. 3, 25–89 (Academic Press, New York, 1980).

I pushed myself up onto my elbow. That was news to me. Felix and Egidia always told me Father had been killed by a bullet to the head. “Luca tortured him?” Schröder, K. et al. Tetrabenzo[ a,c,g,i]fluorenyllithium and η 5-tetrabenzo[ a,c,g,i]fluorenyl-titanium complexes. Organometallics 25, 3824–3836 (2006). Yamada, K. et al. Fulvalene derivatives containing a tetrabenzofluorene unit: new nonplanar fulvalenes with high electron affinity. Synlett 27, 2085–2090 (2016). H={E}_{{{{{{\rm{elec}}}}}}}+{{{{{\rm{ZPE}}}}}}+({H}_{{{{{{\rm{vib}}}}}}}+{H}_{{{{{{\rm{trans}}}}}}}+{H}_{{{{{{\rm{rot}}}}}}}+{{{{{\rm{RT}}}}}})\) Cyclic voltammetry I lay in Nino’s arms, overwhelmed by his confession, our breathing ragged from…making love? We’d made love. Nino had told me he loved me, really loved me, no fake emotion, nothing false, just love.